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Electrocnemistry



Multiple Choice
Identify the choice that best completes the statement or answers the question.
 

 1. 

Which of the following is the INCORRECT statement?
a.
The oxidation number of chlorine atoms in Cl2 is zero.
b.
Oxidation results in an increase in oxidation number.
c.
The oxidizing agent in a redox reaction is reduced.
d.
Electrons are being transferred in a redox reaction.
e.
Reduction is a loss of electrons.
 

 2. 

Which substance is being oxidized in the following reaction?
2 HCl(aq) + Zn(s)  ® ZnCl2(aq) + H2(g)
a.
H+(aq) ions
b.
Cl-(aq) ions
c.
Zn (s)
d.
Zn2+(aq) ions
e.
H2(g)
 

 3. 

What is the oxidation number of Cr in K2Cr2O7?
a.
+2
b.
+3
c.
+7
d.
+6
e.
+5
 

 4. 

Which of the following is the INCORRECT statement?
a.
Reduction results in a decrease in oxidation number.
b.
The oxidation number of oxygen atoms in ozone, O3, is zero.
c.
Reduction is a loss of electrons.
d.
The oxidizing agent in a redox reaction is reduced.
e.
Electrons are being transferred in a redox reaction.
 

 5. 

Which substance is being oxidized in the following reaction?
Zn(s) + 4 CN-(aq) + Ag2CrO4(s) ® [Zn(CN) 4]2- + 2 Ag(s) + CrO42-(aq)
a.
CN- (aq) ions
b.
Ag(s)
c.
Zn(s)
d.
Ag+(aq) ions
e.
H2 (g)
 

 6. 

What is the oxidation number of Cl in HClO2?
a.
-1
b.
+2
c.
+4
d.
+5
e.
+3
 

 7. 

Identify the INCORRECT statement in the following:
a.
One Faraday of charge will reduce exactly one mole of Zn2+ ions to Zn(s).
b.
In an electrolytic cell a nonspontaneous reaction is made to take place by applying an external electric current.
c.
The cathode is the site of reduction in an electrochemical cell.
d.
Measuring the potential of a cell provides a direct determination of the free energy of the cell reaction.
e.
Sodium metal and chlorine gas are produced in an electrolytic cell containing pure molten NaCl.
 

 8. 

How many grams of Ag(s) could be plated out on the cathode of an electrolytic cell by the passage of 5.0 Amps of current through AgNO3 solution for 1 hour? Faraday's number = 96485 Coul/mol.
a.
5.5 x 10-3 g
c.
5.2 x 10-5 g
b.
0.19 g
d.
20 g
 

 9. 

Copper can exist in solution as Cu+ or Cu2+. Suppose a 1.00 Amp current applied for 30.0 minutes produced 1.185 grams of Cu(s). What oxidation state is the copper in solution?
a.
+2
c.
0
b.
+1
d.
cannot tell
 

 10. 

Referring to the table of Standard Cell Potentials below, determine the standard cell potential for the following reaction:
Pb2+(aq) + 2 Cl-(aq) ® Pb(s) + Cl2
Standard reduction potential E°
Pb2+(aq)  +  2e-  ®  Pb(s)     -0.126
Cl2  +  2e-  ® 2 Cl-(aq)         +1.360
a.
+1.486
c.
+1.234
b.
-1.486
d.
-1.234
 

 11. 

Which metal is most easily oxidized to its cationic form?
a.
Ag
c.
Na
b.
Cu
d.
Pb
 

 12. 

In the Daniell cell the overall reaction is:
Zn(s) + Cu2+(aq) ® Zn2+(aq) + Cu(s)
Which of the following reactions is taking place at the cathode?
a.
Cu2+(aq) + 2e- ® Cu(s)
c.
Cu(s) ® Cu2+(aq) + 2e-
b.
Zn(s) ® Zn2+(aq) + 2e-
d.
Zn2+(aq) + 2e- ® Zn(s)
 



 
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